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A General and Highly Selective Method for the Asymmetric Synthesis of Trifluoromethyl‐Substituted α ‐ and β ‐Aminophosphonates
Author(s) -
Wang Lijing,
Shen Qilong,
Lu Long
Publication year - 2013
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201300344
Subject(s) - chemistry , trifluoromethyl , combinatorial chemistry , organic chemistry , alkyl
A highly selective method for the asymmetric formation of trifluoromethyl‐substituted α ‐ and β ‐aminophosphonates was described. The reaction proceeded with high yields and good to excellent diastereoselectivity. The product can be easily converted into corresponding trifluoromethyl‐substituted aminophosphoric acids.