Synthesis of Guanidines from Amines and Carbodiimides Catalyzed by Mono‐Indenyl‐Ligated Rare Earth Metal Bis(silylamide) Complexes | Zendy

Chen Jue | Zendy; Wang Yibin | Zendy; Luo Yunjie | Zendy

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Synthesis of Guanidines from Amines and Carbodiimides Catalyzed by Mono‐Indenyl‐Ligated Rare Earth Metal Bis(silylamide) Complexes

Author(s) -

Chen Jue,

Wang Yibin,

Luo Yunjie

Publication year - 2013

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.201300302

Subject(s) - chemistry , catalysis , nucleophile , rare earth , metal , primary (astronomy) , nitrogen , medicinal chemistry , combinatorial chemistry , polymer chemistry , organic chemistry , mineralogy , physics , astronomy

Nucleophilic addition of primary aromatic amines to carbodiimides in the presence of catalytic amount of the mono‐indenyl‐ligated rare earth metal bis(silylamide) complexes (C 9 H 6 CMe 2 CH 2 C 5 H 4 N‐ α )Ln[N(SiHMe 2 ) 2 ] 2 at room temperature afforded efficiently a series of guanidines with a wide spectrum of substituents on the nitrogen atoms.

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