Enantioselective and  α ‐Regioselective Allylic Amination of Morita‐Baylis‐Hillman Acetates with Simple Aromatic Amines Catalyzed by Planarly Chiral Ligand/Palladium Catalyst | Zendy

Wang Yan | Zendy; Zhang Tao | Zendy; Liu Li | Zendy

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Enantioselective and α ‐Regioselective Allylic Amination of Morita‐Baylis‐Hillman Acetates with Simple Aromatic Amines Catalyzed by Planarly Chiral Ligand/Palladium Catalyst

Author(s) -

Wang Yan,

Zhang Tao,

Liu Li

Publication year - 2012

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.201200771

Subject(s) - chemistry , regioselectivity , amination , enantioselective synthesis , allylic rearrangement , catalysis , ligand (biochemistry) , palladium , organic chemistry , combinatorial chemistry , receptor , biochemistry

An asymmetric allylic amination of Morita‐Baylis‐Hillman acetates with simple aromatic amines catalyzed by planarly chiral ligand/palladium‐catalyst was developed in good yield with excellent α ‐regioselectivity ( α / γ up to 30:1) and moderate enantioselectivity (up to 70% ee ).

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