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Enantioselective Synthesis of Terminal 1,2‐Diols from Acyl Chlorides
Author(s) -
Shao Panlin,
Shen Litao,
Ye Song
Publication year - 2012
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201200697
Subject(s) - chemistry , enantioselective synthesis , terminal (telecommunication) , organic chemistry , stereochemistry , combinatorial chemistry , catalysis , telecommunications , computer science
Optically active terminal 1,2‐diols were prepared with high enantiopurity via the TMS‐quinidine‐catalyzed enantioselective cyclization of acyl chlorides and oxaziridine, followed by reductive ring‐opening of the cycloadducts.