Responsive Gels with the Polymer Containing Alternating Naphthalene Diimide and Fluorinated Alkyl Chains: Gel Formation and Responsiveness as Well as Electrical Conductivity of Polymer Thin Films | Zendy

Luo Hewei | Zendy; Liu Zitong | Zendy; Cai Zhengxu | Zendy; Wu Liusuo | Zendy; Zhang Guanxin | Zendy; Liu Chenyang | Zendy; Zhang Deqing | Zendy

Premium

Responsive Gels with the Polymer Containing Alternating Naphthalene Diimide and Fluorinated Alkyl Chains: Gel Formation and Responsiveness as Well as Electrical Conductivity of Polymer Thin Films

Author(s) -

Luo Hewei,

Liu Zitong,

Cai Zhengxu,

Wu Liusuo,

Zhang Guanxin,

Liu Chenyang,

Zhang Deqing

Publication year - 2012

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.201200029

Subject(s) - chemistry , alkyl , polymer , diimide , naphthalene , polymer chemistry , thin film , side chain , spin coating , conductivity , photochemistry , coating , organic chemistry , molecule , nanotechnology , materials science , perylene

A new electroactive polymer 1 with alternating NDI (naphthalene diimide) moieties and fluorinated alkyl chains was prepared and characterized. Gels of polymer 1 were formed in several solvents. Interestingly, gels of polymer 1 exhibited responsiveness toward N 2 H 4 , F − and CN − . Absorption and ESR spectroscopic studies revealed that such responsiveness is owing to the reduction of NDI moieties into the respective NDI .− . In addition, thin films of polymer 1 were easily prepared with spin‐coating technique and the electrical conductivity of thin films reached 52.4 S/m after exposure to N 2 H 4 vapor.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research