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Studies Directed toward Synthesis of the Structure Proposed for Stereocalpin A
Author(s) -
Huang Yixian,
Wu Yikang
Publication year - 2011
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201190221
Subject(s) - chemistry , stereocenter , aldol reaction , stereochemistry , combinatorial chemistry , organic chemistry , enantioselective synthesis , catalysis
Some synthetic efforts directed to the proposed structure of stereocalpin A are disclosed. The stereogenic centers in the aldol unit were installed using the method of Evans and the intermediates obtained through a reliable route helped to reveal that the spectroscopic data reported earlier in the literature for the same structures were either erroneous or irrelevant. This article is corrected by: On the Synthesis of Stereocalpin A: Partial Retraction/Correction of Previous Results and Rationalization of the Hidden Difficulties, Volume 35, Issue 7, 1185–1194, Article first published online: 6 April 2017.