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Stereoselective Synthesis of 1‐Aminocyclopropanecarboxylic Acid Derivatives via Ylide Cyclopropanation of Dehydroamino Acid Derivatives
Author(s) -
Zhou Rui,
Deng Xianming,
Zheng Juncheng,
Sheng Qi,
Sun Xiuli,
Tang Yong
Publication year - 2011
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201190202
Subject(s) - ylide , chemistry , cyclopropanation , stereoselectivity , sulfur , organic chemistry , catalysis
1‐Aminocyclopropanecarboxylic acid derivatives are synthesized from readily available dehydroamino acid derivatives via sulfur ylide. A range of different ylides are employed and the corresponding aminocyclopropanes are afforded with reasonable diastereoselection in good yields.