Highly Stereoselective Synthesis of 1,2‐Diorganothio‐1‐alkenes via Hydrothiolation of Alkynyl Sulfides Catalyzed by Cesium Hydroxide | Zendy

Tan Ping | Zendy; Yin Xianhong | Zendy; Yu Aihe | Zendy; Qiu Renhua | Zendy; Peng Lifen | Zendy; Xu Xinhua | Zendy; Zhao Yalei | Zendy; Tang Ruiren | Zendy

Premium

Highly Stereoselective Synthesis of 1,2‐Diorganothio‐1‐alkenes via Hydrothiolation of Alkynyl Sulfides Catalyzed by Cesium Hydroxide

Author(s) -

Tan Ping,

Yin Xianhong,

Yu Aihe,

Qiu Renhua,

Peng Lifen,

Xu Xinhua,

Zhao Yalei,

Tang Ruiren

Publication year - 2011

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.201190154

Subject(s) - chemistry , catalysis , caesium , hydroxide , stereoselectivity , alkene , organic chemistry , combinatorial chemistry , medicinal chemistry

In the presence of catalytic amount of cesium hydroxide, the hydrothiolation of alkynyl sulfides occurred at room temperature in DMF under nitrogen atmosphere to afford exclusive ( Z )‐1,2‐diorganothio‐1‐alkene in excellent yields. It could provide a new and expedient way for the preparation of symmetrical and unsymmetrical ( Z )‐1,2‐diorganolthio1‐1‐alkenes.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research