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Synthesis and Characterization of Antimony(III) Complexes of Thioamides, and Crystal Structure of {[Sb(Imt) 2 Cl 2 ] 2 ( ( 2 ‐Imt)}Cl 2 (Imt=Imidazolidine‐2‐thione)
Author(s) -
Ajaz Humayun,
Hussain Sajjad,
Altaf Muhammad,
StoeckliEvans Helen,
Isab Anvarhusein A.,
Mahmood Rashid,
Altaf Shahnila,
Ahmad Saeed
Publication year - 2011
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201190074
Subject(s) - antimony , chemistry , thiourea , molecule , chalcogen , crystal structure , octahedron , sulfur , crystallography , thioamide , stereochemistry , inorganic chemistry , organic chemistry
Antimony(III) complexes of thioamides [thioamides=thiourea (Tu), N , N′ ‐dimethylthiourea (Dmtu), tetramethylthiourea (Tmtu), imidazolidine‐2‐thione (Imt) and diazinane‐2‐thione (Diaz)] with the general formulae, Sb(thione) n Cl 3 ( n =1, 2, 2.5, 3) were prepared and characterized by elemental analysis, IR and NMR ( 1 H, 13 C) spectroscopic methods. The spectral data of the complexes are consistent with the coordination of the thiones to antimony(III). The crystal structure of one of them, {[Sb(Imt) 2 Cl 2 ] 2 ( μ 2 ‐Imt)}Cl 2 ( 1 ), was determined by X‐ray crystallography, which shows that the complex is dinuclear consisting of two [Sb(Imt) 2 Cl 2 ] units bridged by an Imt molecule. In 1 , the antimony atom is bonded to two chlorine atoms, two sulfur atoms of coordinated Imt molecules and one sulfur atom of a bridging Imt molecule. The antimony environment can be considered to be distorted octahedral with one Cl − ion weakly bound to antimony.