Electrosynthesis and Characterization of Poly( N ‐(9‐fluorenylmethoxycarbony)‐glycine) | Zendy

He Yu | Zendy; Guo Wenjuan | Zendy; Pei Meishan | Zendy; Zhang Guangyou | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Electrosynthesis and Characterization of Poly( N ‐(9‐fluorenylmethoxycarbony)‐glycine)

Author(s) -

He Yu,

Guo Wenjuan,

Pei Meishan,

Zhang Guangyou

Publication year - 2012

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.201100283

Subject(s) - chemistry , boron trifluoride , electrosynthesis , acetonitrile , electrochemistry , thermal stability , polyfluorene , nuclear chemistry , inorganic chemistry , polymer , organic chemistry , catalysis , copolymer , electrode

High‐quality poly( N ‐(9‐fluorenylmethoxycarbony)‐glycine) (PFG), a new kind of soluble polyfluorene derivative, was successfully synthesized electrochemically by direct anodic oxidation of N ‐(9‐fluorenylmethoxycarbony)‐glycine (FG) in boron trifluoride diethyl etherate (BFEE). The onset oxidation potential of FG in BFEE was only 0.6 V vs. Pt, which was much lower than that in acetonitrile +0.1 mol/L tetrabutylammonium tetra?uoroborate (TBATFB). PFG film obtained from BFEE showed good electrochemical activity and thermal stability. It indicates that BFEE is a better medium for the electrosynthesis of PFG film. PFG is highly soluble in common organic solvents, facilitating potential applications as a blue‐light‐emitting material. Fluorescent spectra revealed that PFG was a good blue‐light emitter. Results of FT‐IR and 1 H NMR spectra indicated the polymerization location of N ‐(9‐fluorenylmethoxycarbony)‐glycine occurred mainly at C(2) and C(7) positions of the fluorine ring.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research