z-logo
Premium
Study on the Reactions of 3‐Bromo‐4‐ethoxy‐1,1,1‐trifluoro‐ 3‐buten‐2‐one with Benzenethiols Promoted by InCl 3 ·4H 2 O
Author(s) -
Zhao Jingwei,
Song Tao,
Jiang Huiling,
Xu Liangzhong,
Zhu Shizheng
Publication year - 2010
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201090275
Subject(s) - chemistry , alkoxy group , reactivity (psychology) , medicinal chemistry , product (mathematics) , substitution reaction , stereochemistry , organic chemistry , alkyl , medicine , alternative medicine , geometry , mathematics , pathology
Abstract In the presence of InCl 3 ·4H 2 O, the reaction of 3‐bromo‐4‐ethoxy‐1,1,1‐trifluoro‐3‐buten‐2‐one 2 with a series of benzenethiols proceeds readily and gave both the addition‐elimination product 3‐bromo‐1,1,1‐trifluoro‐4‐thiophenyl‐but‐3‐en‐2‐one and substitution product 1,1,1‐trifluoro‐3,4‐bis‐thiophenyl‐but‐3‐en‐2‐one. The reactivity of benzenethiols is discussed in terms of their substituted group.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here