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Highly Selective Potentiometric Oxalate Ion Sensors Based on Ni(II) Bis‐( m ‐aminoacetophenone)ethylenediamine
Author(s) -
Rawat Aruna,
Chandra Sulekh,
Sarkar Anjana
Publication year - 2010
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201090198
Subject(s) - chemistry , ethylenediamine , oxalate , potentiometric titration , detection limit , ion selective electrode , inorganic chemistry , electrode , selectivity , ion , ionophore , membrane , chromatography , organic chemistry , catalysis , biochemistry
A plasticized PVC (polyvinyl chloride) membrane based oxalate ion selective electrode has been developed by using the condensation product of m ‐aminoacetophenone and ethylenediamine. The transition metal complexes of the ligand N , N′ ‐bis( m ‐aminoacetophenene)ethylenediamine (L) were synthesized and incorporated as ionophore for the synthesis of oxalate ion selective electrodes. Most appropriate result in terms of dynamic range, detection limit and response behavior was determined for the Ni(II) bis‐( m ‐aminoacetophenone)ethylenediamine complex. The electrode demonstrated higher selectivity for oxalate ion with improved performance as compared to other carriers reported in past. The electrode shows Nernstian slope of (−28.5±0.4) mV·decade −1 with improved linear range of 1×10 −1 −1×10 −7 mol·L −1 , with a comparatively lower detection limit in the pH range of 5–10.5, giving a relatively fast response within 10 s and reasonable reproducibility. The selectivity coefficient was calculated using matched potential method and fixed interference method. The lifetime of the electrode was found to be nearly 2 months. The response mechanism and the interaction of oxalate ion with the complexes have been discussed by UV‐visible spectroscopic technique. Further the electrode was also successfully applied to determine the oxalate content in water samples.