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First Reaction of a Chiral Gly‐Ni(II) Complex in Water
Author(s) -
Liu Guannan,
Zhou Yu,
Ding Xiao,
Wang Jiang,
Jiang Hualiang,
Liu Hong
Publication year - 2010
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201090090
Subject(s) - chemistry , stereospecificity , aqueous medium , aqueous solution , amination , nickel , reaction conditions , broad spectrum , combinatorial chemistry , organic chemistry , catalysis
The amination of a chiral Ni(II) complex as a model reaction was studied to develop a highly practical, efficient, and stereospecific approach for Ni(II) complex reactions in an aqueous phase. A convenient and clean water‐mediated reaction of the Ni(II) complex has been reached, and a broad spectrum of substrates could participate in the process effectively to produce desired products in good yields and excellent diastereoselectivities. Significantly, it is the first report of chiral gly‐Ni(II) complex reaction in aqueous media.