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Copper(II) and 2,2′‐Biimidazole‐promoted Novel Reaction of 4,4,4‐Trifluoro‐1‐phenylbutane‐1,3‐diones with Iodobenzene Diacetate
Author(s) -
Zhou Chunmei,
Zeng Runsheng,
Zou Jianping
Publication year - 2010
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201090069
Subject(s) - chemistry , iodobenzene , yield (engineering) , copper , organic chemistry , medicinal chemistry , catalysis , metallurgy , materials science
A new and efficient way was developed to carry out the reaction of 4,4,4‐trifluoro‐1‐phenylbutane‐1,3‐dione with iodobenzene diacetate under the assistance of Cu(II) and 2,2′‐biimidazole at a low temperature in excellent yield. 2‐Acetoxyacetophenone was obtained unexpectedly.