Copper(I) Oxide Catalyzed Formation of CS Bond Mediated by  N , N′ ‐Type Ligand | Zendy

Feng Yisi | Zendy; Zhao Xiaoyang | Zendy; Wang Jueyu | Zendy; Zheng Fayin | Zendy; Xu Huajian | Zendy

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Copper(I) Oxide Catalyzed Formation of CS Bond Mediated by N , N′ ‐Type Ligand

Author(s) -

Feng Yisi,

Zhao Xiaoyang,

Wang Jueyu,

Zheng Fayin,

Xu Huajian

Publication year - 2009

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.201090019

Subject(s) - chemistry , ligand (biochemistry) , halide , catalysis , aryl , copper , coupling (piping) , medicinal chemistry , oxide , combinatorial chemistry , polymer chemistry , stereochemistry , organic chemistry , receptor , metallurgy , biochemistry , alkyl , materials science

1,10‐Phenanthroline, a simple and cheap N , N′ ‐type ligand, was found to work well as the ligand of CS coupling catalyzed by Cu 2 O. The corresponding coupling products were synthesized in good to excellent yields (75%–99%) in DMSO at 80°C. A variety of aryl halides and thiols were investigated and satisfactory results were obtained.

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