Premium
Hydrothermal Synthesis, Crystal Structures of Three New Metal(II) Complexes with 1‐Adamantaneacetic Acid
Author(s) -
Geng Xiaohong,
Kong Lichun,
Zheng Jufang,
Feng Yunlong,
Su Hong
Publication year - 2009
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201090004
Subject(s) - chemistry , crystallography , supramolecular chemistry , octahedron , intermolecular force , hydrogen bond , deprotonation , hydrothermal synthesis , crystal structure , metal , hydrothermal circulation , stereochemistry , molecule , ion , organic chemistry , seismology , geology
Three new complexes constructed by 1‐adamantaneacetic acid (HL), [Zn 2 L 4 ] n ( 1 ), [MnL 2 (4,4′‐bipy)(H 2 O) 2 ] n · 2 n (HL) ( 2 ) and MnL 2 (2,2'‐bipy)(H 2 O) 2 ( 3 ), have been hydrothermally synthesized. X‐ray single crystal diffraction analyses reveal that both 1 and 2 are infinite 1D chains along b axis. 2 and 3 have an octahedral coordination and show the supramolecular structures which are formed on the basis of the connectivity of intermolecular hydrogen bonds. The deprotonated L − ligands coordinate the M(II) atoms with many coordination modes in the title complexes.