Synthesis and Crystal Structures of Two Complexes [Mn 2 (L) 2 (H 2 bta) 2 (H 2 O)]  n   and [Cu 2 (L)(H 2 bta) 0.5 (H 2 O)]  n | Zendy

Liu Ruiping | Zendy; Yang Xuwu | Zendy; Wang Lijun | Zendy; Liu Fei | Zendy; Zhang Lingling | Zendy; Yu Fushan | Zendy; Chen Sanping | Zendy

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Synthesis and Crystal Structures of Two Complexes [Mn 2 (L) 2 (H 2 bta) 2 (H 2 O)] n and [Cu 2 (L)(H 2 bta) 0.5 (H 2 O)] n

Author(s) -

Liu Ruiping,

Yang Xuwu,

Wang Lijun,

Liu Fei,

Zhang Lingling,

Yu Fushan,

Chen Sanping

Publication year - 2009

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.200990307

Subject(s) - chemistry , crystallography , stacking , supramolecular chemistry , crystal structure , hydrogen bond , hydrothermal synthesis , benzene , single crystal , x ray crystallography , stereochemistry , hydrothermal circulation , diffraction , molecule , physics , optics , organic chemistry , seismology , geology

Two new complexes, [Mn 2 (L) 2 (H 2 bta) 2 (H 2 O)] n ( 1 ) and [Cu 2 (L)(H 2 bta) 0.5 (H 2 O)] n ( 2 ) (H 4 bta=1,2,4,5‐benzene‐tetracarboxylic acid, L=imidazo[4,5‐ f ][1,10]phenathroline) were prepared under hydrothermal conditions and their structures determined by single‐crystal X‐ray diffration. The X‐ray diffraction reveals that complex 1 , consisting of two crystallographically independent fragments A1 and A2, displays an interesting 3D supramolecular network constructed with ABAB sequence through hydrogen bonding interactions. In complex 2 , the copper atoms connected by the H 2 bta 2− ligands, the chains also are assembled into a 3D honeycomb configuration network formed by moleculars and aromatic π‐π stacking interactions.

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