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Interpenetrating 2D Manganese(II) Coordination Polymer Supported by 4,4′‐Bis(dimethoxyphosphorylmethyl)‐biphenyl Ligands
Author(s) -
ZHANG Xiangdong,
GE Chunhua,
YIN Jing,
ZHAO Yang,
HE Cui
Publication year - 2009
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200990201
Subject(s) - chemistry , thermogravimetric analysis , supramolecular chemistry , biphenyl , manganese , hydrogen bond , coordination polymer , crystal structure , crystallography , polymer , luminescence , infrared spectroscopy , thermal stability , metal organic framework , single crystal , molecule , organic chemistry , physics , optoelectronics , adsorption
A novel coordination polymer [Mn(bdpbp) 2 (NO 3 ) 2 ] n ( 1 ), where bdpbp=4,4′‐bis(dimethoxyphosphoryl‐ methyl)biphenyl, was prepared under mild condition. The structure has been determined by single‐crystal X‐ray diffraction analyses and further characterized by elemental analyses, IR spectra, luminescent property and thermogravimetric analyses. Structure of 1 exhibits infinite grid frameworks and forms two fold interpenetrating nets. Weak C–H···O hydrogen bonds ensure the formation and stability of a three dimensional supramolecular network.