Transfer Hydrogenation of Acetophenone Catalyzed by  in situ  Generated 2,6‐Bis(5‐thioxo‐4,5‐dihydro‐1,2,4‐triazole‐3‐yl)pyridine‐ruthenium(II) Complexes | Zendy

CET?N Ahmet | Zendy; DAYAN Osman | Zendy

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Transfer Hydrogenation of Acetophenone Catalyzed by in situ Generated 2,6‐Bis(5‐thioxo‐4,5‐dihydro‐1,2,4‐triazole‐3‐yl)pyridine‐ruthenium(II) Complexes

Author(s) -

CET?N Ahmet,

DAYAN Osman

Publication year - 2009

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.200990166

Subject(s) - acetophenone , chemistry , ruthenium , transfer hydrogenation , catalysis , pyridine , in situ , ligand (biochemistry) , triazole , medicinal chemistry , organic chemistry , biochemistry , receptor

2,6‐Bis(5‐thioxo‐4,5‐dihydro‐1,2,4‐triazole‐3‐yl)pyridines ( 3 , 4 ) were used for the first time as ligand in ruthenium catalyzed transfer hydrogenation of acetophenone. The in situ prepared three‐component system Ru(II)/tridentate triamine ligands ( 3a – 3d , 4a – 4d ) and KOH catalysed the transfer hydrogenation reaction of acetophenone in good yields under mild conditions.

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