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Transformation of Oximes and Alcohols to Carbonyl Compounds Using Amberlite IRA‐400 Supported Chromic Acid in the Presence of Zirconium Tetrachloride
Author(s) -
BAHRAMI Kiumars,
KHODAEI MohammadMehdi,
GORGINKARAJI Usef
Publication year - 2009
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200990063
Subject(s) - chemistry , chromic acid , hydrazone , titanium tetrachloride , aldehyde , acetonitrile , acetal , alkene , organic chemistry , amberlite , zirconium , catalysis , adsorption
A wide variety of oximes and alcohols were efficiently converted to their corresponding aldehydes and ketones in good to excellent yields using amberlite IRA‐400 supported chromic acid in the presence of zirconium tetrachloride in refluxing acetonitrile‐H 2 O. Selective oxidation of oximes and alcohols in the presence of other functional groups such as acetal, hydrazone, aldehyde, ether and alkene can be considered as a noteworthy advantage of this method. A wide variety of oximes and alcohols were efficiently converted to their corresponding aldehydes and ketones in good to excellent yields using amberlite IRA‐400 supported chromic acid in the presence of zirconium tetrachloride in refluxing acetonitrile‐H 2 O. Selective oxidation of oximes and alcohols in the presence of other functional groups such as acetal, hydrazone, aldehyde, ether and alkene can be considered as a noteworthy advantage of this method.