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Synthesis of Tonghaosu Analogues
Author(s) -
SUN Hai,
LIN Yingjie,
WU Yulin,
WU Yikang
Publication year - 2009
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200990010
Subject(s) - chemistry , enone , dehydration , combinatorial chemistry , organic chemistry , stereochemistry , biochemistry
Several new analogues of natural antifeedant tonghaosu were synthesized via m ‐CPBA ( m ‐chloroperoxybenzoic acid) oxidation of corresponding 3‐( α ‐furyl)propanols, Luche reduction of the resulting enone, epoxidation, acid‐ mediated spiroketalization, and radical mediated dehydration.