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Studies on the Reactions of Fluoroalkylazides with Electron‐deficient Alkenes
Author(s) -
SUN QingRui,
CHEN ZiXian,
LI Shan,
WU YongMing,
TIAN WeiSheng
Publication year - 2008
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200890339
Subject(s) - chemistry , cycloaddition , diazo , ring (chemistry) , medicinal chemistry , computational chemistry , mechanism (biology) , photochemistry , electron , dipole , organic chemistry , catalysis , quantum mechanics , physics
The 1,3‐dipolar cycloaddition of fluoroalkylazides with electron deficient olefins was studied. A series of fluoroalkylated triazoline and pyrazolines were synthesized by this method. A ring opening and diazo intermediate mechanism was proposed.