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Formation of Two‐dimensional Metal‐water Framework Containing (H 2 O) 20 Cluster
Author(s) -
SUN YaGuang,
DING Fu,
GU XiaoFu,
ZHANG WanZhong,
WEI DeZhou,
GAO EnJun
Publication year - 2008
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200890332
Subject(s) - chemistry , hydrogen bond , gravimetric analysis , crystallography , solvent , crystal structure , water cluster , infrared spectroscopy , cluster (spacecraft) , metal , distilled water , maleic acid , thermogravimetric analysis , ethanol , elemental analysis , inorganic chemistry , nuclear chemistry , molecule , organic chemistry , polymer , chromatography , computer science , programming language , copolymer
[Cd(phen) 2 (male)(H 2 O)]·9.5H 2 O ( 1 ) has been synthesized by the reaction of Cd(NO 3 ) 2 with phen and male (phen=1,10‐phenanthroline, H 2 male=maleic acid) in a mixture solvent of ethanol and distilled water. The complex was characterized by elemental analysis, infrared spectrum and thermal gravimetric analyses. The crystal structure was determined by X‐ray single‐crystal diffraction. In 1 , a novel 1D water chain containing water (H 2 O) 20 cluster was formed. Further hydrogen bonding interaction between the water chain and [Cd(phen) 2 (male)(H 2 O)] constructs a unique metal‐water 2D framework.