Water as a Direct Hydrogen Donor in Supercritical Carbon Dioxide: A Novel and Efficient Zn‐H 2 O‐CO 2  System for Chemo‐selective Reduction of Nitrobenzenes to Anilines | Zendy

JIANG HuanFeng | Zendy; DONG YaoSen | Zendy

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Water as a Direct Hydrogen Donor in Supercritical Carbon Dioxide: A Novel and Efficient Zn‐H 2 O‐CO 2 System for Chemo‐selective Reduction of Nitrobenzenes to Anilines

Author(s) -

JIANG HuanFeng,

DONG YaoSen

Publication year - 2008

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.200890256

Subject(s) - chemistry , nitrobenzene , supercritical carbon dioxide , carbon dioxide , supercritical fluid , hydrogen , electrochemical reduction of carbon dioxide , solvent , environmentally friendly , carbon fibers , inorganic chemistry , organic chemistry , catalysis , carbon monoxide , ecology , biology , materials science , composite number , composite material

An eco‐friendly and cheap Zn‐H 2 O‐CO 2 system was presented for chemoselective reduction of nitrobenzenes to anilines with high yields (80% –97% isolated yields) in supercritical carbon dioxide. This process brings together the very important green chemistry technologies–the use of carbon dioxide as a solvent and the use of water as a hydrogen donor.

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