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Reduction of NO 2 in Flue Gas by CO and Propylene over CuO‐CeO 2 /SiO 2 in the Presence of O 2
Author(s) -
LU MoHong,
LI MingShi,
SHAN YuHua,
SESHAN K.,
LEFFERTS Leon
Publication year - 2008
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200890184
Subject(s) - chemistry , propylene oxide , catalysis , flue gas , selective catalytic reduction , inorganic chemistry , oxygen , impurity , organic chemistry , ethylene oxide , copolymer , polymer
Catalytic reduction of NO 2 with CO and/or propylene in the presence of NO and excess oxygen, a model mixture for flue gas, was studied over a series of CuO‐CeO 2 /SiO 2 catalysts between 120–260 °C. The effect of HCl, an impurity in flue gas, on the activity of the catalysts was evaluated. It was found that a binary oxide catalyst, 2% CuO‐8% CeO 2 /SiO 2 , was active for the reduction of NO 2 by CO and/or propylene. CO was effective for selective reduction of NO 2 in the presence of NO and O 2 in a temperature window between 160–200 °C while propylene was effective at temperature higher than 200 °C. In the presence of HCl, the activity of the catalyst for reduction of NO 2 with CO was irreversibly deactivated. However, the activity for reduction of NO 2 with propylene was not influenced by HCl.