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Preparation of Magnetic Photocatalyst TiO 2 Supported on NiFe 2 O 4 and Effect of Magnetic Carrier on Photocatalytic Activity
Author(s) -
XU ShiHong,
FENG DaoLun,
LI DengXin,
SHANGGUAN WenFeng
Publication year - 2008
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200890156
Subject(s) - photocatalysis , methyl orange , rutile , chemistry , nanoparticle , transmission electron microscopy , chemical engineering , magnetic nanoparticles , degradation (telecommunications) , magnetic hysteresis , nanotechnology , materials science , catalysis , magnetization , magnetic field , organic chemistry , telecommunications , computer science , engineering , physics , quantum mechanics
A magnetic photocatalyst TiO 2 /NiFe 2 O 4 (TN) with typical ferromagnetic hysteresis was prepared by a sol‐gel method, which is easy to be separated from a slurry‐type photoreactor under the application of an external magnetic field, being one of promising photocatalysts for wastewater treatment. The analysis of XRD indicated that the highly dispersed NiFe 2 O 4 nanoparticles prevented the formation of rutile phase to some extent. A transmission electron microscope (TEM) was used to characterize the structure of the photocatalyst, indicating that the NiFe 2 O 4 nanoparticles highly dispersed among TiO 2 nanoparticles. The prepared photocatalyst showed high photocatalytic activity for the degradation of methyl orange in water. The degradation results revealed that the NiFe 2 O 4 nanoparticles played the role of recombination centre of photogenerated electrons and holes for the TN photocatalyst, which gave rise to the decrease in photocatalytic activity. Moreover, the experiment on recycled use of TN demonstrated a good repeatability of the photocatalytic activity.