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A New Route to Preparations of Silyl Ethers by Reactions of Silyl Triflimides with Alcohol or Ether
Author(s) -
TANG ZiLong
Publication year - 2008
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200890099
Subject(s) - chemistry , silylation , silyl ether , silanes , alcohol , ether , organic chemistry , medicinal chemistry , catalysis , silane
A few of acyclic and cyclic silyl ethers were firstly synthesized in good yields by reactions of silyl triflimides with alcohol or ether. The corresponding silyl triflimides were easily produced by protodesilylation of phenyl or allyl silanes with HNTf 2 . All new compounds were characterized by 1 H NMR, 13 C NMR, MS, IR and HRMS.