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Studies on Chromatographic Properties of Perhydroxycucurbit[6]uril as a New Type of Gas Chromatographic Column Packing Material
Author(s) -
LI LaiSheng,
WANG ShangWen,
CHEN XiongQuan,
LIU Chao,
XU LiLi
Publication year - 2008
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200890060
Subject(s) - chemistry , chromatography , boiling point , thermostability , selectivity , stationary phase , gas chromatography , structural isomer , column (typography) , organic chemistry , catalysis , structural engineering , connection (principal bundle) , engineering , enzyme
Perhydroxycucurbit[6]uril {(HO) 12 CB[6]} has been used successfully as a stationary phase for packed column gas chromatography for the first time. Perhydroxycucurbit[6]uril stationary phase (PSP) exhibited wide operational temperature, outstanding thermostability and good selectivities to various organic compounds, such as alkanes, aromatic hydrocarbons, alcohols, esters, ketones, amines, etc . It was also found that some positional isomers, such as disubstituted benzenes could be well separated on this column. PSP has excel1ent separation abilities to some complicate samples, for example, commercial toilet water. Some mechanism of the new packing for GC‐separation was preliminarily discussed. It was observed that the partial inclusion complexation of PSP with analytes could improve separation selectivity and column efficiency, instead of complete inclusion. Moreover, PSP exhibited low baseline shift even at dramatically programmed temperature for complicate samples covering a wide boiling point range so as to fast assay.