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N ‐Heterocyclic Carbene‐Palladium Complex Catalyzed Oxidative Carbonylation of Amines to Ureas
Author(s) -
Zheng ShuZhan,
Peng XinGao,
Liu JianMing,
Sun Wei,
Xia ChunGu
Publication year - 2007
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200790196
Subject(s) - chemistry , carbene , palladium , carbonylation , aniline , catalysis , oxidative phosphorylation , oxidative addition , medicinal chemistry , combinatorial chemistry , organic chemistry , carbon monoxide , biochemistry
Abstract Palladium carbene shows high efficiency without any promoter on oxidative carbonylation of amines to ureas and a new type of palladium carbene complex containing both an aniline and an NHC ligands was found to be the active species for the reaction.