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Effects of some Nitrogen Bases on the Oxygenation of Tetralin with Sodium Periodate Catalyzed by Manganese(III) meso ‐Tetraphenylporphyrin as a Model Compound of Cytochrome P‐450
Author(s) -
Reza Tayebee
Publication year - 2007
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200790165
Subject(s) - chemistry , tetralin , tetraphenylporphyrin , sodium periodate , pyridine , catalysis , manganese , imidazole , ligand (biochemistry) , medicinal chemistry , selectivity , inorganic chemistry , organic chemistry , porphyrin , biochemistry , receptor
The effect of some nitrogen bases on the oxygenation of tetralin by sodium periodate, catalyzed by Mn(TPP)OAc, was evaluated. A series of eight bases, including imidazole, pyridine, and quinuclidine, was used. Binding of axial ligand to the four‐coordinate Mn(III)‐center influenced the efficiency and selectivity of the catalytic oxygenation system.