Liquid‐Phase Synthesis of Methyl (2 Z )‐2‐Arylsulfonylmethyl‐2‐ alkenoates from PEG‐Supported  α ‐Phenylselenopropionate | Zendy

Wang Qiong | Zendy; Sheng ShouRi | Zendy; Lin ShuYing | Zendy; Guo Lei | Zendy; Wei MeiHong | Zendy; Huang Xian | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Liquid‐Phase Synthesis of Methyl (2 Z )‐2‐Arylsulfonylmethyl‐2‐ alkenoates from PEG‐Supported α ‐Phenylselenopropionate

Author(s) -

Wang Qiong,

Sheng ShouRi,

Lin ShuYing,

Guo Lei,

Wei MeiHong,

Huang Xian

Publication year - 2007

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.200790164

Subject(s) - chemistry , peg ratio , hydrogen peroxide , derivative (finance) , medicinal chemistry , sodium , organic chemistry , finance , financial economics , economics

Treatment of lithio derivative of novel PEG‐supported (‐phenylselenopropionate with aldehydes, followed by oxidation‐elimination with 30% hydrogen peroxide, formed Baylis‐Hillman products, which were then reacted with sodium arylsulfinate. The resulting sulfonylated products were cleaved from the PEG efficiently affording methyl (2 Z )‐2‐arylsulfonylmethyl‐2‐alkenoates in good yields and high purities.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research