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Tris(2,2′‐bipyridyl) Ruthenium(II) Doped Silica Film Modified Indium Tin Oxide Electrode and Its Electrochemiluminescent Properties
Author(s) -
Wei Hui,
Du Yan,
Kang JianZhen,
Xu GuoBao,
Wang ErKang
Publication year - 2007
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200790032
Subject(s) - chemistry , ruthenium , electrochemiluminescence , silane , indium tin oxide , electrode , tin , inorganic chemistry , indium , tris , oxide , tin oxide , polymer chemistry , coating , catalysis , organic chemistry , biochemistry
An approach was reported to synthesize silica hybridized ruthenium bipyridyl complex through amidation reaction by covalent attachment of bis(bipyridyl)‐4,4′‐dicarboxy‐2,2′‐bipyridyl‐ruthenium to (3‐aminopropyl)‐triethoxy‐ silane. The hybrid complex then was gelatinized through acid catalytic hydrolysis method and a sol‐gel modified indium tin oxide electrode was prepared via spin coating technique. As prepared indium tin oxide electrode possesses good stability therein with excellent electrochemiluminescence behavior.