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Dicyano‐Functionalized MCM‐41‐Supported Palladium Complex as An Efficient Catalyst for Allylation of Aldehydes and Ketones
Author(s) -
Zhao Hong,
Cai MingZhong
Publication year - 2006
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200690313
Subject(s) - chemistry , palladium , allylic rearrangement , catalysis , mcm 41 , chloride , aldehyde , organic chemistry , ketone , polymer chemistry , combinatorial chemistry , molecular sieve
Dicyano‐functionalized MCM‐41‐supported palladium complex was prepared from dicyano‐functionalized MCM‐41 and palladium chloride. This complex exhibited high catalytic activity in the allylation of aldehydes and ketones with allylic chlorides in the presence of SnCl 2 . This polymeric palladium complex can be recovered and reused without noticeable loss of activity.