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Asymmetric Allyltributylstannane Addition to Ketones Catalyzed by Chiral Indium(III)‐PYBOX Complex
Author(s) -
Lu Jun,
Ji ShunJun
Publication year - 2006
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200690270
Subject(s) - chemistry , indium , oxazoline , catalysis , pyridine , enantioselective synthesis , combinatorial chemistry , medicinal chemistry , organic chemistry
An indium complex of chiral pyridine bis(oxazoline) (PYBOX) has been applied to the catalytic asymmetric allylation of ketones. It has been found that this chiral indium complex is strong enough to promote the reaction of ketones with allyltributylstannane smoothly. The products were obtained in moderate yields with low to moderate enantioselectivities.