Premium
Aggregation of Dodecyl 1‐Pyrenylmethyl Ether and Its Application in Structure‐Polarity Relations of Aggregates †
Author(s) -
Sang DaYong,
Tian Juan,
Ji GuoZhen
Publication year - 2006
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200690209
Subject(s) - chemistry , polarity (international relations) , ether , fluorescence , solvent polarity , chain (unit) , chromatography , organic chemistry , photochemistry , biochemistry , physics , quantum mechanics , astronomy , cell , solvent
The aggregation behavior of dodecyl 1‐pyrenylmethyl ether was studied in dioxane‐water mixture solvents by fluorescence techniques. The labeled pyrenyl group was effective in monitoring the polarity change of its environment during aggregation processes. Based on the structural effects such as chain‐length effect, self‐coiling effect, and branch‐group effect on the polarity of the probe environment, the structure features of aggregates were discussed and have been used to interpret the effect of the structural features on the aggregates formed by three cholesteryl esters and three long chain alkanes.