Premium
Synthesis and Characterization of 8‐Hydroxyquinoline Derivative Containing a Triphenylamine Unit and Its Metal Complexes
Author(s) -
Jing HuiLian,
Zeng HePing,
Zhou YaDong,
Wang TingTing,
Yuan GuoZan,
Ouyang XinHua
Publication year - 2006
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200690183
Subject(s) - chemistry , 8 hydroxyquinoline , spectroscopy , derivative (finance) , elemental analysis , zinc , copper , infrared spectroscopy , thermogravimetry , metal , nuclear magnetic resonance spectroscopy , ligand (biochemistry) , triphenylamine , nuclear chemistry , inorganic chemistry , photochemistry , stereochemistry , organic chemistry , biochemistry , physics , receptor , quantum mechanics , financial economics , economics
A new 8‐hydroxyquinoline derivative ( 5 ) was synthesized and characterized by ESI‐MS, 1 H NMR spectroscopy, elemental analysis and IR spectroscopy. The photophysical properties of compounds 5 , 6 and 7 were also detemined by UV‐vis and FL spectroscopy. The vibrational frequency of ligand 5 predicted by using B3LYP method is in good agreement with experimentally determined values. The compositions of the corresponding copper(II) and zinc(II) complexes were confirmed to be Cu(C 29 H 21 N 2 O) 2 ·H 2 O ( 6 ) and Zn(C 29 H 21 N 2 O) 2 ·H 2 O ( 7 ) by elementary analysis, thermogravimetry analysis and IR spectroscopy.