Synthesis and Characterization of 8‐Hydroxyquinoline Derivative Containing a Triphenylamine Unit and Its Metal Complexes | Zendy

Jing HuiLian | Zendy; Zeng HePing | Zendy; Zhou YaDong | Zendy; Wang TingTing | Zendy; Yuan GuoZan | Zendy; Ouyang XinHua | Zendy

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Synthesis and Characterization of 8‐Hydroxyquinoline Derivative Containing a Triphenylamine Unit and Its Metal Complexes

Author(s) -

Jing HuiLian,

Zeng HePing,

Zhou YaDong,

Wang TingTing,

Yuan GuoZan,

Ouyang XinHua

Publication year - 2006

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.200690183

Subject(s) - chemistry , 8 hydroxyquinoline , spectroscopy , derivative (finance) , elemental analysis , zinc , copper , infrared spectroscopy , thermogravimetry , metal , nuclear magnetic resonance spectroscopy , ligand (biochemistry) , triphenylamine , nuclear chemistry , inorganic chemistry , photochemistry , stereochemistry , organic chemistry , biochemistry , physics , receptor , quantum mechanics , financial economics , economics

A new 8‐hydroxyquinoline derivative ( 5 ) was synthesized and characterized by ESI‐MS, 1 H NMR spectroscopy, elemental analysis and IR spectroscopy. The photophysical properties of compounds 5 , 6 and 7 were also detemined by UV‐vis and FL spectroscopy. The vibrational frequency of ligand 5 predicted by using B3LYP method is in good agreement with experimentally determined values. The compositions of the corresponding copper(II) and zinc(II) complexes were confirmed to be Cu(C 29 H 21 N 2 O) 2 ·H 2 O ( 6 ) and Zn(C 29 H 21 N 2 O) 2 ·H 2 O ( 7 ) by elementary analysis, thermogravimetry analysis and IR spectroscopy.

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