Reduction of Azide to Amine Using Fe/AlCl 3  or Fe/BiCl 3  System in Aqueous EtOH | Zendy

Zheng PengWu | Zendy; Xie XueMin | Zendy; Wang Wei | Zendy; Wang XiaoJi | Zendy; Guo YuPing | Zendy; Tu QiDong | Zendy

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Reduction of Azide to Amine Using Fe/AlCl 3 or Fe/BiCl 3 System in Aqueous EtOH

Author(s) -

Zheng PengWu,

Xie XueMin,

Wang Wei,

Wang XiaoJi,

Guo YuPing,

Tu QiDong

Publication year - 2006

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.200690157

Subject(s) - chemistry , aqueous solution , amine gas treating , azide , ethanol , lewis acids and bases , reduction (mathematics) , metal , inorganic chemistry , organic chemistry , catalysis , geometry , mathematics

Azides were reduced to the corresponding amines by two new metal/Lewis acid systems in aqueous EtOH with yields ranging from 80% to 95%. The new reduction systems were Fe/AlCl 3 ·6H 2 O or Fe/BiCl 3 system in H 2 O/ethanol (2:1, V : V ) at room temperature. Fifteen azides with different functional groups were well reduced to the corresponding amines in excellent yields.

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