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Estimation of the Kinetic Parameters and the Critical Rate of Temperature Rise in the Thermal Explosion from the Exothermic Autocatalytic Decomposition of 3,4‐Bis(4′‐nitrofurazan‐3′‐yl)‐2‐oxofurazan (BNFOF) Using Non‐isothermal Differential Scanning Calorimetry
Author(s) -
Zhao FengQi,
Guo PengJiang,
Hu RongZu,
Zhang Hai,
Xia ZhiMing,
Gao HongXu,
Chen Pei,
Luo Yang,
Zhang ZhiZhong,
Zhou YanShui,
Xiao Qin,
Zhao HongAn,
Gao ShengLi,
Shi QiZhen,
Lu GuiE,
Jiang JinYong
Publication year - 2006
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200690121
Subject(s) - autocatalysis , chemistry , exothermic reaction , thermal decomposition , kinetic energy , isothermal process , thermodynamics , decomposition , differential scanning calorimetry , autocatalytic reaction , order of reaction , thermal , reaction rate , kinetics , rate equation , reaction rate constant , organic chemistry , catalysis , statistical physics , classical mechanics , physics
A method of estimating the kinetic parameters and the critical rate of temperature rise in the thermal explosion for the autocatalytic decomposition of 3,4‐bis(4′‐nitrofurazan‐3′‐yl)‐2‐oxofurazan (BNFOF) with non‐isothermal differential scanning calorimetry (DSC) was presented. The rate equation for the decomposition of BNFOF was established, and information was obtained on the rate of temperature increase in BNFOF when the empiric‐order autocatalytic decomposition was converted into thermal explosion.