Synthesis, Photochromic Kinetics, Fluorescence and Structure of a New 1,2‐Diarylcyclopentene | Zendy

Pu ShouZhi | Zendy; Xiao Qiang | Zendy; Xu JingKun | Zendy; Shen Liang | Zendy; Li GuiZhen | Zendy; Chen Bing | Zendy

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Synthesis, Photochromic Kinetics, Fluorescence and Structure of a New 1,2‐Diarylcyclopentene

Author(s) -

Pu ShouZhi,

Xiao Qiang,

Xu JingKun,

Shen Liang,

Li GuiZhen,

Chen Bing

Publication year - 2006

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.200690089

Subject(s) - photochromism , chemistry , diarylethene , kinetics , fluorescence , photochemistry , chemical kinetics , optics , physics , quantum mechanics

The photochromic diarylethene, 1,2‐bis[2‐methyl‐5‐(3‐trifluoromethylphenyl)‐3‐thienyl]perfluorocyclopentene (BMTTP), was synthesized and its photochromic kinetics, fluorescence and X‐ray structure were investigated. This compound underwent a photochromic reaction both in solution and the single crystalline phase. Its cyclization/cycloreversion process was determined to be zeroth/first order reaction, respectively, and this is the first report on the cyclization/cycloreversion reaction order. In addition, its fluorescence property was also discussed.

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