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The First Total Synthesis of the (±)‐Palstatin
Author(s) -
Feng JianPeng,
Wang XiaoLong,
Cao XiaoPing
Publication year - 2006
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200690041
Subject(s) - chemistry , total synthesis , oxidative phosphorylation , oxidative coupling of methane , catalysis , combinatorial chemistry , organic chemistry , biochemistry
The first total synthesis of (±)‐palstatin was achieved from commercially available 5‐bromovanallin and 2,4,6‐trihydroxyacetophenone. SeO 2 promoted oxidative cyclization reaction and Ag 2 O catalyzed oxidative coupling reaction served as the key steps in the synthesis successfully.