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An Efficient Enantioselective Synthesis of Blastmycinone
Author(s) -
Yang YongQing,
Wu YiKang
Publication year - 2005
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200591519
Subject(s) - chemistry , enantioselective synthesis , combinatorial chemistry , key (lock) , degradation (telecommunications) , organic chemistry , catalysis , biology , ecology , telecommunications , computer science
Blastmycinone, a degradation product of the antibiotic antimycin A, was synthesized with a TiCl 4 ‐mediated asymmetric aldolization as the key step. Some unexpected yet interesting chemistry was also observed.