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Intramolecular C→N 1,3‐Migration of Alkoxycarbonyl or Acetyl Group‐Applications, Limitations and Mechanism
Author(s) -
Yuri G Gololobov
Publication year - 2005
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200591103
Subject(s) - chemistry , intramolecular force , electrophile , carbon atom , mechanism (biology) , stereochemistry , group (periodic table) , medicinal chemistry , atom (system on chip) , ring (chemistry) , organic chemistry , catalysis , philosophy , epistemology , computer science , embedded system
A new type of intramolecular electrophilic rearrangements involving the shift of alkoxycarbonyl or acetyl groups from a carbon atom to an N‐anionic center is presented.