Syntheses and Complexation Properties of Novel Macrocyclic Molecular Receptors: Tetrahomodioxacalix[6]arene Derivatives | Zendy

HaiBing Li | Zendy; YuanYin Chen | Zendy; XiangLiang Yang | Zendy

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Syntheses and Complexation Properties of Novel Macrocyclic Molecular Receptors: Tetrahomodioxacalix[6]arene Derivatives

Author(s) -

HaiBing Li,

YuanYin Chen,

XiangLiang Yang

Publication year - 2005

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.200590891

Subject(s) - chemistry , ethyl bromoacetate , calixarene , selectivity , lithium (medication) , ion , transition metal , stereochemistry , combinatorial chemistry , medicinal chemistry , organic chemistry , molecule , medicine , endocrinology , catalysis

Several tetrahomodioxacalix[6]arene hexaesters, hexaacid and hexaamide derivatives were synthesized from tetrahomodioxacalix[6]arene by etherification with ethyl bromoacetate. It was found that p ‐ tert ‐butyltetrahomodioxacalix[6]arene hexaethylester exhibited high selectivity towards lithium ion. p ‐ tert ‐Butyltetrahomodioxacalix[6]arene hexaamides showed high ion‐binding ability towards transition metal ions.

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