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Reductive Cleavage of the Carbon‐sulfur Bond by Samarium/Cp 2 TiCl 2 System for the Synthesis of Dialkyl Disulfides
Author(s) -
XueShun Jia,
YongMin Zhang
Publication year - 2005
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200590303
Subject(s) - chemistry , samarium , sulfur , cleavage (geology) , samarium diiodide , carbon fibers , bond cleavage , combinatorial chemistry , organic chemistry , catalysis , geotechnical engineering , fracture (geology) , composite number , engineering , materials science , composite material
A mild and rapid method was found for the reductive cleavage of the carbon‐sulfur bond in the alkylthiocyanates by samarium/Cp 2 TiCl 2 system to give the corresponding dialkyl disulfides in moderate to good yields.