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Hydrothermal Synthesis and Structure of K 3 Na 5 (H 2 NCH 2 CH 2 NH 3 ) 2 {(VO) 12 O 6 [B 3 O 6 (OH)] 6 }(H 2 O)·12H 2 O
Author(s) -
Bin Lu,
Hong Wang,
Li Zhang,
ChengYong DAI,
QingHai Cai,
YongKui Shan
Publication year - 2005
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.200590137
Subject(s) - monoclinic crystal system , chemistry , crystallography , hydrothermal synthesis , crystal structure , molecule , ion , x ray crystallography , group (periodic table) , center (category theory) , hydrothermal circulation , stereochemistry , diffraction , physics , organic chemistry , optics , seismology , geology
A new compound containing polyoxovanadoborate anion was synthesized and characterized by single‐crystal X‐ray diffraction analysis. A water molecule at the center of the anion was precisely determined. The crystals of the new compound belong to the monoclinic system, space group P2 1 / n with a =1.35002(7), b =2.0864(1), c =2.3667(1) nm, β=90.669(1)°, V =6.6660(5) nm 3 , Z =4, µ=2.066 mm −1 , D c =2.352 g/cm 3 , M r =2359.2, S =1.152, R =0.0642, wR =0.0789.