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Electrolytic fixation of CO 2 by electrocarboxylation of rx on nanocrystalline TiO 2 ‐Pt cathode
Author(s) -
Chu DaoBao,
Li XiaoHua,
Liu XinYuan,
Yao WenLi
Publication year - 2004
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20040221104
Subject(s) - chemistry , nanocrystalline material , cyclic voltammetry , electrochemistry , halide , cathode , electrolyte , electrolysis , electrode , inorganic chemistry , supporting electrolyte , crystallography
Electrolytic fixation of CO 2 was investigated by electrocarboxylation of organic halides (a), and four esters (I, II, III, IV) were obtained in moderate yields. Electrochemical reduction esterifications of RX in the presence of CO 2 were carried out on nanocrystalline TiO 2 ‐Pt electrode. The electrochemical behavior of RX in the presence of CO 2 was investigated by the technique of cyclic voltammetry, and the probable reaction mechanism was proposed.