Syntheses and crystal structures of benzyltin(IV) derivatives of 2‐mercaptobenzothiazole | Zendy

Zhang RuFen | Zendy; Qiu LinLin | Zendy; Li Feng | Zendy; Ma ChunLin | Zendy

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Syntheses and crystal structures of benzyltin(IV) derivatives of 2‐mercaptobenzothiazole

Author(s) -

Zhang RuFen,

Qiu LinLin,

Li Feng,

Ma ChunLin

Publication year - 2004

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.20040220731

Subject(s) - chemistry , tin , denticity , trigonal bipyramidal molecular geometry , crystallography , ligand (biochemistry) , chelation , crystal structure , pentagonal bipyramidal molecular geometry , bipyramid , atom (system on chip) , stereochemistry , crystal (programming language) , x ray crystallography , antimony , diffraction , inorganic chemistry , organic chemistry , physics , biochemistry , receptor , optics , computer science , programming language , embedded system

The complexes (PhCH 2 Sn(MBT) 2 (2) and (PhCH 2 Sn(MBT) (3) (HMBT: 2‐mercaptobenzothiazole) have been synthesized and characterized by elemental analyses, and IR, 1 H, 13 C, 119 Sn NMR spectrometries and X‐ray diffraction. Studies on the crystal structures of 2 and 3 show that HMBT acts as bidentate ligand through chelation of N and S atoms. Complex 2 contains a six‐coordinate tin atom with the axial angle C(15)‐Sn(1)‐C(22) 129.6(2) o . And the tin environment of complex 3 is a distorted cis ‐trigonal bipyramid with C(8)‐Sn(1)‐N(1) 158.80 o .

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