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Synthesis, crystal structure and magnetic properties of a new 30 cobalt vanadate
Author(s) -
Wang Lei,
Zhang Hong,
Zhang JingPing,
Niu Ben,
Cui ShuXin
Publication year - 2004
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20040220705
Subject(s) - vanadate , chemistry , orthorhombic crystal system , cobalt , crystallography , antiferromagnetism , crystal structure , magnetic susceptibility , hydrothermal synthesis , crystal (programming language) , inorganic chemistry , hydrothermal circulation , condensed matter physics , chemical engineering , physics , engineering , programming language , computer science
A new cobalt vanadate compound 1 [Co 11 (H 2 O)2 V V 2 O 6 ] has been hydrothermally synthesized and characterized by the elemental analyses and the single crystal X‐ray diffraction analysis. Compound 1 crystallizes in the orthorhombic system, space group Pmna , with a =0.55646, b= 1.06900, c= 1.18452 nm, and Z=4. The magnetic susceptibility of the cobalt vanadate has been measured and indicates possible antiferromagnetic coupling between adjacent cobalt (II) (0.5432‐0.5697 nm) through bond or space.