Factors Influencing Sulfinatodehalogenation Reactions of Perhalocarbons | Zendy

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Factors Influencing Sulfinatodehalogenation Reactions of Perhalocarbons

Author(s) -

Wu Kai,

Chen QingYun

Publication year - 2004

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.20040220411

Subject(s) - chemistry , solvent , chloride , medicinal chemistry , reaction conditions , inorganic chemistry , nuclear chemistry , organic chemistry , catalysis

The study on the factors influencing sulfinatodehalogenation of perfluorohexyl chloride plus octene‐1 by using Na 2 S 2 O 4 /NaHCO 3 discovered that among the various solvents tested ( e.g . Me 2 SO, NMP, DMAc, CH 3 CN, CH 3 CN/H 2 O) at different temperatures, Me 2 SO was found to be the most suitable solvent and the conversion of the chloride was very dependent on the reaction temperature. When Me 2 SO was used in the reaction of perfluoroalkyl iodides. the reaction temperature could be decreased by 20 °C as compared with that carried out in CH 3 CN/H 2 O to reach the comparable yields.

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