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Synthesis and Crystal Structure of a Puckered Rhombus Grid‐like Coordination Polymer with Bridging Ligand Containing Sulfanyl Linker
Author(s) -
Han Lei,
Luo JunHua,
Hong MaoChun,
Wang RuiHu,
Lin ZhengZhong,
Cao Rong
Publication year - 2004
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20040220112
Subject(s) - chemistry , rhombus , crystallography , linker , bridging ligand , coordination polymer , ligand (biochemistry) , crystal structure , powder diffraction , bridging (networking) , stereochemistry , computer network , biochemistry , geometry , mathematics , receptor , computer science , operating system
A new coordination polymer with sulfide moieties, [Co(ptmb) 2 ] · 0.25H 2 O (ptmb=4–(4‐pyridylthiomethyl)‐benzoate), was synthesized by self‐assembly of Co(NO 3 ) 2 · 6H 2 O with Hptmb under solvothermal conditions. X‐ray single crystal diffraction study shows that it is a 2D layer structure consisting of puckered rhombus grid with dimensions 1.175 nm ×1.110 nm.